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Contact & Quotation

  • Inquire: Call 0086-755-23203480, or reach out via the form below/your sales contact to discuss our design, manufacturing, and assembly capabilities.
  • Quote: Email your PCB files to Sales@pcbsync.com (Preferred for large files) or submit online. We will contact you promptly. Please ensure your email is correct.
Drag & Drop Files, Choose Files to Upload You can upload up to 3 files.

Notes:
For PCB fabrication, we require PCB design file in Gerber RS-274X format (most preferred), *.PCB/DDB (Protel, inform your program version) format or *.BRD (Eagle) format. For PCB assembly, we require PCB design file in above mentioned format, drilling file and BOM. Click to download BOM template To avoid file missing, please include all files into one folder and compress it into .zip or .rar format.

DuPont Pyralux FR: Flame Retardant Flex Laminates — UL Rated, Full Spec Guide

If your flex PCB design needs a UL flammability rating — and a growing number of industrial, telecommunications, and consumer product designs do — DuPont Pyralux FR is the material most fabricators are going to pull off the shelf. It fills a specific and well-defined role in the Pyralux family: acrylic-adhesive flex laminate with certified flame retardancy, built on Kapton polyimide film, processed just like Pyralux LF. This guide walks through the full FR product line, product codes, electrical and mechanical specs, processing notes, and honest comparisons to help you decide where FR belongs in your design — and where it doesn’t.

What Is DuPont Pyralux FR? The Core Value Proposition

DuPont Pyralux FR is a composite of DuPont Kapton polyimide film with copper foil on one or both sides, bonded together with a proprietary, flame-retardant, C-staged acrylic adhesive. Pyralux FR flexible composites are recommended for use in single-sided, double-sided, multilayer, and rigid-flex circuits that require flame retardancy.

That single sentence from DuPont’s own datasheet captures the product’s purpose precisely. It’s a three-layer construction — copper, flame-retardant acrylic adhesive, Kapton polyimide — and its defining characteristic is the UL 94 VTM-0 flammability certification. When your end product has to pass UL 796 or equivalent safety agency testing, and the flex circuit inside it is the component that needs the UL rating, Pyralux FR is your material.

The “FR” designation stands for Flame Retardant, not to be confused with the FR in “FR4” — which is fiberglass/epoxy territory. Pyralux FR is an all-flex material on Kapton film and processes through standard flex fabrication equipment. It is not a rigid PCB material.

For DuPont PCB applications where regulatory compliance drives material selection, Pyralux FR is DuPont’s commercial-grade answer for industrial and telecommunications applications requiring certified flame retardancy at a cost structure that makes production economics work.

The Full DuPont Pyralux FR Product Ecosystem

Like Pyralux LF, the FR series is a complete matched material ecosystem covering every functional layer in a flex PCB stack-up. This matters because you want consistent adhesive chemistry throughout your construction — mixing FR coverlay over LF laminate, for example, defeats the purpose of specifying flame-retardant materials if the UL certification is based on the full composite assembly.

Pyralux FR Copper-Clad Laminate (CCL)

The CCL is the base circuit substrate. Copper foil is bonded to one or both sides of Kapton polyimide film using the flame-retardant acrylic adhesive system. All copper-clad laminates are available with rolled-annealed (RA) copper or electro-deposited (ED) copper. In addition, both types are available with double-treated copper — nodules of electro-deposited copper on both sides of the copper foil — which, if used, eliminates surface preparation steps prior to resist or coverlay lamination.

That double-treated copper option is a real process efficiency gain in high-volume production. Skipping the surface prep step before coverlay lamination reduces cycle time and eliminates one source of surface contamination risk.

Pyralux FR Coverlay

Pyralux FR coverlay composites are constructed of DuPont Kapton polyimide film coated on one side with a proprietary flame-retardant B-staged acrylic adhesive. They are used to encapsulate etched details in flexible and rigid-flex multilayer constructions for environmental and electrical protection.

Critical note for designers: when the finished assembly requires UL certification, your coverlay must also carry the UL flame retardancy rating. Specifying standard Pyralux LF coverlay over FR laminate would leave the encapsulation layer uncertified — a problem that surfaces during UL testing and causes failures that are expensive to redesign around.

Pyralux FR Bondply

Bondply carries the same flame-retardant B-staged acrylic adhesive on both sides of the Kapton film. It is the interlayer bonding material for multilayer flex constructions. When you’re pressing a multilayer rigid-flex stack with FR materials throughout, bondply goes between each inner flex layer pair, maintaining the all-FR material chain from core to surface.

Pyralux FR Sheet Adhesive

Pyralux FR sheet adhesive is a proprietary flame-retardant B-staged modified acrylic adhesive coated on release paper. Sheet adhesive is used primarily to bond flexible innerlayers or rigid cap layers in multilayers. It can also be used to bond flexible circuits to rigid boards during the fabrication of rigid-flex circuits, as well as to bond stiffeners and heat sinks.

The flame-retardant formulation here is particularly important for rigid-flex assemblies where sheet adhesive is bonding the rigid FR4 cap layer to the flex core. If your product requires a full UL 94 rated construction, this bond layer needs to be FR-grade, not standard LF sheet adhesive.

DuPont Pyralux FR Product Codes and Construction Options

Understanding the FR part number system follows the same logic as Pyralux LF. The copper type suffix at the end of the product code tells you the foil specification:

  • “R” = Rolled-Annealed (RA) copper — e.g., FR9210R
  • “E” = Electro-Deposited (ED) copper — e.g., FR9210E
  • “D” = Double-Treated Rolled-Annealed copper — e.g., FR9210D

Pyralux FR CCL Construction Options

Polyimide Thickness µm (mil)Copper Thickness µm (oz/ft²)Copper Types Available
12 (0.5)17 (0.5), 35 (1.0), 70 (2.0)RA, ED, DT
25 (1.0)17 (0.5), 35 (1.0), 70 (2.0)RA, ED, DT
50 (2.0)17 (0.5), 35 (1.0), 70 (2.0)RA, ED, DT
75 (3.0)17 (0.5), 35 (1.0), 70 (2.0)RA, ED, DT
125 (5.0)17 (0.5), 35 (1.0), 70 (2.0)RA, ED, DT

Certified to IPC-4204/1: “Flexible Metal-Clad Dielectrics for Use in Fabrication of Flexible Printed Wiring.”

Pyralux FR Coverlay and Bondply Construction Options

Polyimide Thickness µm (mil)Adhesive Thickness µm (mil)IPC Certification
12 (0.5)12, 25, 50, 75 µmIPC-4203A/1
25 (1.0)12, 25, 50, 75 µmIPC-4203A/1
50 (2.0)12, 25, 50, 75 µmIPC-4203A/1
75 (3.0)12, 25, 50, 75 µmIPC-4203A/1
125 (5.0)12, 25, 50, 75 µmIPC-4203A/1

Pyralux FR Sheet Adhesive Product Codes

Product CodeAdhesive Thickness mil (µm)IPC CertificationUL 94 VTM-0
FR01001.0 (25)YesYes
FR02002.0 (51)YesYes
FR03003.0 (76)YesYes
FR04004.0 (102)YesYes
FR15000.5 (13)YesYes

Sheet adhesive is certified to IPC-4203/18. FR0200 and FR0300 specifically meet UL 94 VTM-0 criteria per published test data.

Key Electrical and Mechanical Properties of Pyralux FR

The following data is based on typical values from DuPont’s official Pyralux FR datasheets. The reference construction for most published data is 1 oz RA copper / 1 mil adhesive / 1 mil Kapton.

Electrical Properties

PropertyTypical ValueTest Method
Dielectric Constant (1 MHz)3.5 maxIPC-TM-650 No. 2.5.5.3
Dissipation Factor (1 MHz)0.04 maxIPC-TM-650 No. 2.5.5.3
Dielectric Strength3,000 V/mil (118 kV/mm)ASTM D-149
Surface Resistivity10⁶ MΩASTM D-257
Volume Resistivity10⁹ MΩ·cmASTM D-257
Insulation Resistance10⁷ MΩIPC-TM-650 No. 2.6.3.2

Mechanical and Thermal Properties

PropertyTypical ValueTest Method / Standard
UL Flammability RatingVTM-0UL 94
Meets UL 796 Direct SupportYesUL 796
UL Maximum Operating Temp (MOT)105°CUL
Peel Strength (after lamination)1.6 N/mm (9 lb/in)IPC-TM-650 No. 2.4.9
Peel Strength (after soldering)1.6 N/mm (9 lb/in)IPC-TM-650 No. 2.4.9
Solder Float ResistancePass (10 sec at 288°C)IPC-TM-650 No. 2.4.13
Adhesive Flow10.0 mils/mil of adhesiveIPC-TM-650 No. 2.3.17.1
Dimensional StabilityPer IPC-4204/1IPC-TM-650 No. 4.6.2
Multiple Lamination CyclesNo degradation
Refrigeration RequiredNoRoom temperature storage
Product Warranty2 years from manufacture

A few specifics worth unpacking from an engineering perspective:

UL Maximum Operating Temperature of 105°C — this is the temperature at which UL has certified the material for continuous service. It’s set by the acrylic adhesive layer, not the Kapton film (which handles temperatures well above this). This is a key design constraint for any application with elevated steady-state operating temperature — vehicle interiors can approach this limit in worst-case summer scenarios, for example.

Peel strength of 1.6 N/mm maintained after soldering — this tells you the bond doesn’t degrade after the assembly reflow process. It’s an important qualification for any design where the flex circuit goes through an assembly soldering step before being installed in the final product.

Dissipation factor of 0.04 — same characteristic as Pyralux LF, driven by the acrylic adhesive layer. At frequencies below 1 GHz this is generally manageable. For designs pushing into higher frequency bands, this is the spec that would send you toward Pyralux AP or the TA/TK series materials.

UL Rating Explained: Why It Matters for Pyralux FR

The UL 94 VTM-0 rating is the specification that separates Pyralux FR from Pyralux LF in most design decisions. Understanding what this rating actually means prevents misapplication.

UL 94 is Underwriters Laboratories’ standard for flammability of plastic materials used in devices and appliances. The VTM-0 classification applies specifically to very thin materials (too thin for the standard vertical burn test) and requires that:

  • Flaming and glowing combustion stops within 30 seconds after each of five flame applications
  • No dripping of flaming particles that ignite cotton below the specimen

UL 796 Direct Support certification means the material is approved for use as a substrate in direct contact with current-carrying conductors — a requirement that many end-product certifications mandate for the PCB substrate itself.

UL Maximum Operating Temperature (MOT) of 105°C is the rated continuous service temperature. Products carrying a UL Recognized Component mark using Pyralux FR will reference this temperature rating in their UL file.

With a UL MOT of 105°C, FR is the product of choice for designs with UL 94 VTM-0 rating requirements — particularly in consumer power electronics, industrial controls, and telecommunications infrastructure where safety agency certification is non-negotiable.

DuPont Pyralux FR vs. Other Flex Laminates: Head-to-Head

Pyralux FR vs. Pyralux LF — The Key Tradeoff

FactorPyralux FRPyralux LF
Adhesive TypeFlame-retardant acrylicStandard acrylic
UL 94 RatingVTM-0VTM-0*
Halogen-FreeNoYes
RoHS CompliantYesYes
ProcessingIdentical to LFStandard
UL MOT105°C105°C
Best ForUL-rated productsHalogen-free designs
CostSlightly higher than LFBaseline acrylic cost

*Note: Pyralux LF also achieves VTM-0, but without the halogen-based flame retardant chemistry. The practical question is whether your supply chain, customer specification, or regional regulation requires halogen-free status — if yes, LF; if UL certification with no halogen restriction, FR is the validated path.

Pyralux FR vs. Pyralux AP — Performance vs. Certification

FactorPyralux FRPyralux AP
Construction3-layer (adhesive-based)2-layer (adhesiveless)
Loss Tangent~0.04~0.002
Tg (adhesive layer)~100°C (acrylic)220°C (polyimide)
UL FlammabilityVTM-0V-0 / VTM-0
Lead-Free ReflowUse with careExcellent
Fine Pitch CapabilityStandardHigh
CostModerateHigher
Primary StrengthUL certification, costHigh-frequency, high-reliability

The honest comparison: if your product has to carry a UL mark and cost constraints are real, Pyralux FR is the right specification. If your product is a military avionics box, a 5G mmWave module, or a multilayer rigid-flex medical instrument where reflow reliability over 10+ years is the design driver, Pyralux AP is the correct material and the cost premium is justified.

Industry Applications: Where Pyralux FR Gets Specified

Pyralux FR is a commercial-grade product ideal for industrial and telecommunications applications requiring flame retardancy. Here’s how that maps to specific use cases:

Industry / ApplicationPyralux FR RoleKey Driver
Consumer power adapters and chargersFlex circuit inside UL-listed power supplyUL 94 VTM-0 required for listing
Telecommunications infrastructureBase station flex interconnects, switching equipmentUL 796 Direct Support compliance
Industrial controls and automationFlex cable assemblies in control panelsSafety agency requirements
Office and home appliancesInternal flex connectors in UL-listed productsProduct-level UL certification
LED lighting assembliesFlexible circuit substrate for LED strips with UL markUL 94 VTM-0 + thermal resistance
Rigid-flex backplanesInner flex layers requiring flame retardancySystem-level fire safety standard
Automotive cabin electronicsNon-underhood flex interconnects in UL-certified modulesModerate temperature, UL compliance

A practical note from the design side: one of the most common errors is specifying Pyralux LF for a product that eventually needs UL certification, then discovering during the listing process that the PCB material isn’t in the UL component database with the required rating. Catching this at the material selection stage — and specifying Pyralux FR from the start — prevents a costly material change late in development.

Fabrication and Processing Notes for Pyralux FR

Standard Lamination Conditions

Pyralux FR can be processed like Pyralux LF, which is a practical advantage if your fab shop already runs LF on its equipment. The standard press lamination parameters are:

  • Part Temperature: 182–199°C (360–390°F)
  • Pressure: 14–28 kg/cm² (200–400 psi)
  • Time: 1–2 hours at temperature

No specialized tooling or unique process chemistry is required beyond what a standard flex shop uses for Pyralux LF.

Adhesive Curing Behavior

The Pyralux FR acrylic adhesive is cured during the lamination step. The curing reaction does not produce any vapors, although impurities may volatilize. This is important to communicate to the press operator: unlike some prepreg systems that outgas significantly during cure, FR lamination doesn’t generate cure reaction by-products — but ambient impurities in the adhesive can volatilize, so adequate ventilation at the press is still standard practice.

Drilling and Routing

Provide adequate vacuum extraction around the drill head when drilling or routing. Polyimide and acrylic adhesive dust are respiratory irritants. Good practice from a quality standpoint as well: swarf contamination in drilled via holes before plating is a direct via reliability risk.

Storage

No refrigeration is required. Store at 4–29°C (40–85°F), below 70% relative humidity, in original packaging, kept dry and protected from physical damage. Shelf life is two years from date of manufacture under these conditions. A Certificate of Compliance (COC) and Certificate of Analysis (CoA) are available with every batch for traceability documentation.

Handling Safety

Pyralux FR flexible circuit materials do not contain polybrominated biphenyls (PBBs) or polybrominated biphenyl oxides (PBBOs), which is worth noting since these are specifically restricted under EU RoHS and REACH regulations. The flame retardancy is achieved through a different halogen-based chemistry that does not use these banned compounds. Personnel should wash hands before eating, smoking, or using facilities, and gloves should be changed daily when handling the material.

Quality, Certifications, and Traceability

DuPont manufactures Pyralux FR under a certified ISO 9001:2015 Quality Management System. Complete material and manufacturing records, including archive samples of finished product, are maintained by DuPont. Each manufactured lot is identified for reference traceability, with the packaging label serving as the primary tracking mechanism in the event of customer inquiry.

The relevant IPC certifications for Pyralux FR:

Product TypeIPC Certification
Copper-Clad LaminateIPC-4204/1
Coverlay / BondplyIPC-4203A/1
Sheet AdhesiveIPC-4203/18

A Certificate of Conformance is available with every batch for all certified constructions. For UL-related procurement, the UL file number for DuPont Pyralux FR materials should be confirmed directly with DuPont or your distributor — the specific file number is needed when populating UL component databases for your end product.

Useful Resources for Engineers Specifying Pyralux FR

ResourceDescriptionLink
DuPont Pyralux FR Official PageOverview, full product listings, datasheet downloadsdupont.com/pyralux-fr
Pyralux FR CCL Datasheet (PDF)Construction table, electrical/mechanical specs, processing guidepyralux.dupont.com
Pyralux FR Coverlay Datasheet (PDF)Coverlay and bondply product codes and typical datapyralux.dupont.com
Pyralux FR Sheet Adhesive Datasheet (PDF)Sheet adhesive product codes, UL VTM-0 datapyralux.dupont.com
DuPont Safe Handling GuideFull safety and processing guidelinespyralux.dupont.com
IPC-4204 SpecificationFlexible metal-clad dielectrics industry standardipc.org
Insulectro Pyralux FRDistributor with product listing, datasheet access, and tech supportinsulectro.com
Epectec Pyralux FR DatasheetDownloadable CCL and coverlay datasheetsepectec.com
PCBSync DuPont PCB HubFlex PCB manufacturing with DuPont materials guidancepcbsync.com/Dupont-pcb

Frequently Asked Questions About DuPont Pyralux FR

Q1: What exactly does the UL 94 VTM-0 rating on Pyralux FR mean, and why is it required?

UL 94 VTM-0 is Underwriters Laboratories’ thin-material flammability classification. It requires the material to self-extinguish within 30 seconds after flame removal in vertical burn testing, with no dripping burning particles. Products that need to carry a UL listing — power supplies, industrial equipment, appliances, telecom hardware — typically need to demonstrate that internal PCB substrates meet this flammability standard. Pyralux FR achieves this through its flame-retardant acrylic adhesive formulation, making it the DuPont flex laminate of choice when UL certification is required on the end product.

Q2: Can DuPont Pyralux FR be processed with the same equipment as Pyralux LF?

Yes — this is one of the most practical advantages of the FR series. Pyralux FR can be processed exactly like Pyralux LF with identical lamination press parameters: 182–199°C, 14–28 kg/cm², 1–2 hours. If your fab shop is already qualified on Pyralux LF, adding FR to your approved materials list requires process qualification documentation but no capital equipment changes. This makes switching between LF and FR for different customer requirements relatively straightforward.

Q3: Does Pyralux FR contain polybrominated biphenyls (PBBs) or other banned flame retardants?

No. Pyralux FR materials do not contain polybrominated biphenyls (PBBs) or polybrominated biphenyl oxides (PBBOs). These specific compounds are banned under EU RoHS. The flame retardancy in Pyralux FR is achieved through a different halogen-based acrylic adhesive chemistry. Note, however, that Pyralux FR is not halogen-free — it does contain halogens as part of the flame retardant mechanism. If halogen-free compliance is a design requirement, specify Pyralux LF instead.

Q4: What IPC specifications should I reference on my fabrication drawing when calling out Pyralux FR?

Reference these IPC specs in your flex PCB fabrication notes depending on which FR component you’re specifying: copper-clad laminate to IPC-4204/1, coverlay and bondply to IPC-4203A/1, and sheet adhesive to IPC-4203/18. A typical fabrication note reads: “Base laminate: DuPont Pyralux FR per IPC-4204/1” with the specific product code and construction in the stack-up table. Your fabricator’s approved material list should confirm Pyralux FR as a qualified source for these specifications.

Q5: What is the UL Maximum Operating Temperature (MOT) of Pyralux FR, and how does it affect design?

The UL MOT for Pyralux FR is 105°C. This is the continuous service temperature at which UL has certified the material. It’s established by the acrylic adhesive layer, which softens as it approaches its glass transition temperature around 100°C. For UL-certified product designs, the thermal management analysis must confirm that the flex circuit operating temperature stays within this 105°C limit under worst-case conditions. Applications where the flex circuit runs close to this temperature — LED driver modules, motor drive flex interconnects, under-hood automotive connections — may need to upgrade to Pyralux AP or HT series materials to maintain both safety certification and long-term reliability.

Final Guidance: Specifying Pyralux FR Correctly

DuPont Pyralux FR occupies a clear and specific position in the flex laminate selection matrix. If your design checklist includes a UL flammability requirement, Pyralux FR is the answer. If it doesn’t — or if your specification requires halogen-free materials — Pyralux LF covers the same application space without the flame-retardant chemistry. If your design pushes above the 105°C UL MOT, or if signal integrity at multi-GHz frequencies is on the critical path, the discussion moves to Pyralux AP.

The mistake to avoid is using Pyralux LF by default and discovering late in the product development cycle that the UL listing process requires an FR-rated substrate. Material selection decisions made early are inexpensive. Material changes made during UL testing are not. Pyralux FR is a commercial-grade, broadly available, standard-process material — there’s no cost penalty for specifying it correctly from day one on any design that needs a UL-rated flex circuit.

For flex PCB manufacturing guidance and sourcing using DuPont materials including Pyralux FR, visit PCBSync’s DuPont PCB resource page.

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Contact Sales & After-Sales Service

Contact & Quotation

  • Inquire: Call 0086-755-23203480, or reach out via the form below/your sales contact to discuss our design, manufacturing, and assembly capabilities.

  • Quote: Email your PCB files to Sales@pcbsync.com (Preferred for large files) or submit online. We will contact you promptly. Please ensure your email is correct.

Drag & Drop Files, Choose Files to Upload You can upload up to 3 files.

Notes:
For PCB fabrication, we require PCB design file in Gerber RS-274X format (most preferred), *.PCB/DDB (Protel, inform your program version) format or *.BRD (Eagle) format. For PCB assembly, we require PCB design file in above mentioned format, drilling file and BOM. Click to download BOM template To avoid file missing, please include all files into one folder and compress it into .zip or .rar format.